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On the relation between virial coefficients and the close-packing of hard disks and hard spheres

机译:关于维里系数与密堆积的关系   硬盘和硬球

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摘要

The question of whether the known virial coefficients are enough to determinethe packing fraction $\eta_\infty$ at which the fluid equation of state of ahard-sphere fluid diverges is addressed. It is found that the informationderived from the direct Pad\'e approximants to the compressibility factorconstructed with the virial coefficients is inconclusive. An alternativeapproach is proposed which makes use of the same virial coefficients and of theequation of state in a form where the packing fraction is explicitly given as afunction of the pressure. The results of this approach both for hard-disk andhard-sphere fluids, which can straightforwardly accommodate higher virialcoefficients when available, lends support to the conjecture that $\eta_\infty$is equal to the maximum packing fraction corresponding to an orderedcrystalline structure.
机译:解决了已知维里系数是否足以确定堆积率$ \ eta_ \ infty $的问题,在该堆积率下硬球流体的流体状态方程发散了。结果发现,从直接的Pad'e近似值到由病毒系数构成的可压缩因子的信息是不确定的。提出了一种替代方法,该方法利用相同的维里系数和状态方程式,其中以压力的函数形式明确给出填充分数。这种方法对硬盘和硬球形流体的结果都可以直接适应更高的病毒系数,从而可以推测$ \ eta_ \ infty $等于对应于有序晶体结构的最大堆积分数。

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